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The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).
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Synthesis and structural characterization of arsinoamide and its metal complexes, Xiao Chen
- Jazyk
- Rok vydania
- 2019
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- Titul
- Synthesis and structural characterization of arsinoamide and its metal complexes
- Jazyk
- anglicky
- Autori
- Xiao Chen
- Vydavateľ
- Cuvillier Verlag
- Vydavateľ
- 2019
- ISBN10
- 373697034X
- ISBN13
- 9783736970342
- Kategórie
- Skriptá a vysokoškolské učebnice
- Anotácia
- The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).